Alright I will make it quick, Primary Key and Unique Key is same, they are not allow to have 2 same value, the different is Primary Key won't allow the field to be empty, but Unique Key are allowed to have empty field.
So if you need identifier that like ID Card, you should use Primary Key because everybody need to have id card, but if you need something for Driving License Card, you should use Unique Key, because no everybody have driving license.
Hope this helpful 😊